How
many states it takes to describe the b-state and the f-state?
A single b(egin)-state
and a single f(inish)-state suffice to describe the process for a uniform
system.
Examples: Work done in compressing a gas in a
piston-cylinder device, heat required to raise the temperature of a block of solid, pressure drop in a closed chamber due to cooling, etc. Browse animations in Animations.5.A for more examples.
There are two uniform
sub-systems
which do not mix and retain their identity in a non-mixing non-uniform system.
Example: In a process in which a hot block of copper comes to thermal equlibrium after being dropped into a tank of water, the sub-systems (A and B) are the copper block and water.
To describe the anchor states of the process, four system states
- bA and bB for the b-state, and fA and fB for the f-state - are
required. The
sub-systems,
A and B, may exchange energy but not mass at any time during the process. Browse animations in Animations.5.B for more examples.
The daemons in this category are very similar to the
mixing (Mixing, Non-Uniform) daemons linked above, except, these allow
the valve to be closed before mixing is complete. Beside the composite
beginning-state consisting of bA and
bB
states, the final state is also composite and consists of fA
and fB states.
Example: Nitrogen and oxygen in two chambers, when allowed to mix
by opening a connecting valve, undergo a semi-mixing process resulting in a composite f-state if the valve is closed before mixing is complete.
Here, too, there are multiple subsystems,
requiring two states, bA and
bB,
to describe the composite b-state.
During the process mass transfer between the sub-systems A and B and
energy transfer (heat and work) with the surroundings result in a
single f-state.
Example: Nitrogen and oxygen in two chambers, when allowed to mix
by opening a connecting valve, undergo a mixing
process resulting in a single f-state, provided
sufficient time is allowed for mixing. Browse animations in Animations.5.C for more examples.
Generic Closed Process and Its Governing Balance Equations